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Chemical element with atomic number 14 (Si)
Silicon, 14 Si A lump of black reflective metal Pronunciation Allotropes see Allotropes of silicon Appearance crystalline, reflective with bluish-tinged faces
Atomic number (Z ) 14 Group group 14 (carbon group) Period period 3 Block p-block Electron configuration [Ne ] 3s2 3p2 Electrons per shell 2, 8, 4 Phase at STP solid Melting point 1687 K (1414 °C, 2577 °F) Boiling point 3538 K (3265 °C, 5909 °F) Density (at 20° C) 2.329085 g/cm3 [ 3] when liquid (at m.p. ) 2.57 g/cm3 Heat of fusion 50.21 kJ/mol Heat of vaporization 383 kJ/mol Molar heat capacity 19.789 J/(mol·K) Specific heat capacity 704.611 J/(kg·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1908
2102
2339
2636
3021
3537
Oxidation states common: −4, +4
−3,[ 6] −2,[ 6] −1,[ 6] 0,[ 4] +1,[ 6] [ 5] +2,[ 6] +3[ 6] Electronegativity Pauling scale: 1.90 Ionization energies 1st: 786.5 kJ/mol 2nd: 1577.1 kJ/mol 3rd: 3231.6 kJ/mol (more ) Atomic radius empirical: 111 pm Covalent radius 111 pm Van der Waals radius 210 pm Color lines in a spectral range Spectral lines of siliconNatural occurrence primordial Crystal structure face-centered diamond-cubic (cF8 ) Lattice constant a = 543.0986 pm (at 20 °C)[ 3] Thermal expansion 2.556× 10−6 /K (at 20 °C)[ 3] Thermal conductivity 149 W/(m⋅K) Electrical resistivity 2.3× 10 3 Ω⋅m (at 20 °C)[ 7] Band gap 1.12 eV (at 300 K) Magnetic ordering diamagnetic [ 8] Molar magnetic susceptibility −3.9× 10−6 cm3 /mol (298 K)[ 9] Young's modulus 130–188 GPa[ 10] Shear modulus 51–80 GPa[ 10] Bulk modulus 97.6 GPa[ 10] Speed of sound thin rod 8433 m/s (at 20 °C) Poisson ratio 0.064–0.28[ 10] Mohs hardness 6.5 CAS Number 7440-21-3 Naming after Latin silex or silicis , meaning 'flint ' Prediction Antoine Lavoisier (1787) Discovery and first isolationJöns Jacob Berzelius [ 11] [ 12] (1823)Named by Thomas Thomson (1817)
File:Symbol category class.svg Category: Silicon | references
child table, as reused in {IB-Si}
References
These references will appear in the article, but this list appears only on this page.
↑ "Standard Atomic Weights: Silicon" . CIAAW . 2009.
↑ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)" . Pure and Applied Chemistry . doi :10.1515/pac-2019-0603 . ISSN 1365-3075 .
↑ 3.0 3.1 3.2 Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements . Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9 .
↑ "New Type of Zero-Valent Tin Compound" . Chemistry Europe . 27 August 2016.
↑ Ram, R. S.; et al. (1998). "Fourier Transform Emission Spectroscopy of the A2D–X2P Transition of SiH and SiD" (PDF) . J. Mol. Spectr . 190 (2): 341– 352. doi :10.1006/jmsp.1998.7582 . PMID 9668026 .
↑ Greenwood, Norman N. ; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 28. doi :10.1016/C2009-0-30414-6 . ISBN 978-0-08-037941-8 .
↑ Eranna, Golla (2014). Crystal Growth and Evaluation of Silicon for VLSI and ULSI . CRC Press. p. 7. ISBN 978-1-4822-3281-3 .
↑ Magnetic susceptibility of the elements and inorganic compounds , in Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton, Florida: CRC Press. ISBN 0-8493-0486-5 .
↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics . Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4 .
↑ 10.0 10.1 10.2 10.3 Hopcroft, Matthew A.; Nix, William D.; Kenny, Thomas W. (2010). "What is the Young's Modulus of Silicon?" . Journal of Microelectromechanical Systems . 19 (2): 229. doi :10.1109/JMEMS.2009.2039697 .
↑ Weeks, Mary Elvira (1932). "The discovery of the elements: XII. Other elements isolated with the aid of potassium and sodium: beryllium, boron, silicon, and aluminum". Journal of Chemical Education . 9 (8): 1386– 1412. Bibcode :1932JChEd...9.1386W . doi :10.1021/ed009p1386 .
↑ Voronkov, M. G. (December 2007). "Silicon era". Russian Journal of Applied Chemistry . 80 (12): 2190– 2196. doi :10.1134/S1070427207120397 .
↑ 13.0 13.1 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF) . Chinese Physics C . 45 (3) 030001. doi :10.1088/1674-1137/abddae .
Four of these are named references . They may be cited in the containing article as
<ref name="Eranna2014" /> for the source by Eranna
<ref name="hopcroft" /> for the source by Hopcroft
<ref name="Voronkov-2007" /> for the source by Voronkov
<ref name="Weeks-1932" /> for the source by Weeks